NCERT Science Notes - Class 10
Chapter 2 - Acids, Bases and Salts

Welcome to our AJs Chalo Seekhen. This webpage is dedicated to Class 10 | Science | Chapter 2 - Acids, Bases and Salts. This chapter provides an insightful exploration of these crucial chemical substances. It introduces students to the fundamental concepts of acids and bases, their properties, and the reactions they undergo. The chapter also delves into the formation and characteristics of salts, a product of reactions between acids and bases. This comprehensive overview is designed to build a strong foundation in understanding these essential components of chemistry, making it a vital part of the curriculum for Class 10th students.

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NOTES

NCERT Science Notes - Class 10
Chapter 2 - Acids, Bases and Salts

    Introduction

    1. Sour and Bitter Tastes: Acids cause sour taste; bases cause bitter taste.
    2. Remedy for Acidity: Baking soda solution is suggested due to its basic nature.
    3. Acid-Base Neutralization: Acids and bases can nullify each other’s effects.
    4. Indicators:
      • Litmus: Natural indicator; blue litmus turns red in acid, red litmus turns blue in base.
      • Turmeric: Turns reddish-brown with bases.
      • Methyl Orange and Phenolphthalein: Synthetic indicators.
    5. Litmus Solution: Purple dye from lichen; purple when neutral.
    6. Other Natural Indicators: Red cabbage leaves, turmeric, certain flower petals.

    2.1.2 How do Acids and Bases React with Metals?

    Activity 2.3

  1. Reaction of Metals with Acids
    1. Caution: This activity requires teacher supervision.
    2. Set up the apparatus as illustrated in Figure 2.1.
        • Take approximately 5 mL of dilute sulfuric acid in a test tube and introduce a few pieces of zinc granules into it.
        • Observe any changes occurring on the surface of the zinc granules.
        • Pass the gas produced during the reaction through a soap solution.
        • Explain why bubbles form in the soap solution.
        • Bring a burning candle near a soap bubble containing the gas.
        • Describe your observations.
        • Repeat this activity using other acids like HCl, HNO3, and CH3COOH.
        • Compare and contrast the observations made with different acids.

          In the reactions described above, the metal displaces hydrogen atoms from the acids, leading to the formation of hydrogen gas and a compound known as a salt. This reaction can be summarized as:
           Acid + Metal → Salt + Hydrogen gas
    3. Now, let's write the equations for the reactions you have observed:
        • Reaction with Dilute Sulfuric Acid (H2SO4):
          • Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g)
          • Reaction with Dilute Hydrochloric Acid (HCl):
            • Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g)
          • Reaction with Dilute Nitric Acid (HNO3):
            • Zn(s) + 2HNO3(aq) → Zn(NO3)2(aq) + H2(g)
          • Reaction with Dilute Acetic Acid (CH3COOH):
            • Zn(s) + 2CH3COOH(aq) → (CH3COO)2Zn(aq) + H2(g)
      In all cases, hydrogen gas is produced as a result of the metal displacing hydrogen from the acids. The specific salt formed depends on the acid used in the reaction.

      Activity 2.4 

      1. Materials Used: Granulated zinc metal, sodium hydroxide (NaOH) solution, test tube.
      2. Procedure: Zinc is added to the NaOH solution in a test tube, which is then warmed.
      3. Chemical Reaction: 2NaOH (aq) + Zn (s) → Na2ZnO2 (s) + H2 (g). This reaction forms sodium zincate (Na2ZnO2) and hydrogen gas (H2).
      4. Concept: Reaction of Metals with Bases
      5. When certain metals react with bases, they can form a metal salt and hydrogen gas. In this specific reaction, granulated zinc reacts with sodium hydroxide (a base) to form sodium zincate and hydrogen gas. The reaction is a demonstration of an amphoteric metal (zinc) reacting with a strong base (sodium hydroxide). Amphoteric metals can react with both acids and bases.
      6. Observations: Formation of hydrogen gas can be observed.
      7. Selectivity of Reaction: Not all metals react in the same way as zinc does with sodium hydroxide.
      8. Chemistry Concept: This reaction demonstrates a metal's reaction with a strong base, resulting in the formation of a metal salt (sodium zincate in this case) and hydrogen gas.
  2. Activity 2.5

    1. Objective: To observe the reaction of sodium carbonate (Na2CO3) and sodium hydrogencarbonate (NaHCO3) with dilute hydrochloric acid (HCl).
    2. Procedure:
      • Sodium carbonate is placed in test tube A and sodium hydrogencarbonate in test tube B.
      • 2 mL of dilute HCl is added to both test tubes.
      • The gas produced in each test tube is passed through lime water.
    3. Chemical Reactions:
      • Test tube A: Na2CO3 + 2HCl(aq)→2NaCl + H2O(l) + CO2(g)
      • Test tube B: NaHCO3(s) + HCl(aq)→NaCl(aq) + H2O(l) + CO2(g)
      • Reaction with lime water: Ca(OH)2(aq) + CO2(g)→CaCO3(s) + H2O(l)
      • Reaction with excess CO2: CaCO3(s) + H2O(l) + CO2(g)→Ca(HCO3)2(aq)
    4. Observations:
      • Bubbling observed in both test tubes, indicating the release of CO2 gas.
      • Passing the gas through lime water turns it milky due to the formation of calcium carbonate. Further passage of CO2 dissolves the precipitate, indicating the formation of calcium hydrogencarbonate.
      • Conclusion: Metal carbonates and hydrogencarbonates react with acids to form a salt, carbon dioxide, and water.

    2.1.3 How do Metal Carbonates and Metal Hydrogencarbonates React with Acids?

    Activity 2.5
    1. Objective: To observe the reaction of Sodium Carbonate (Na2CO3) and Sodium Hydrogencarbonate (NaHCO3) with dilute Hydrochloric Acid (HCl).
    2. Procedure:
      1. Sodium Carbonate is placed in test tube A and Sodium Hydrogencarbonate in test tube B.
      2. 2 mL of dilute HCl is added to both test tubes.
      3. The gas produced in each test tube is passed through lime water.
    3. Chemical Reactions:
      1. Test tube A: Na2CO3 + 2HCl(aq) → 2NaCl + H2O(l) + CO2(g)
      2. Test tube B: NaHCO3(s) + HCl(aq) → NaCl(aq) + H2O(l) + CO2(g)
      3. Reaction with lime water: Ca(OH)2(aq) + CO2(g) → CaCO3(s) + H2O(l)
      4. Reaction with excess CO2: CaCO3(s) + H2O(l) + CO2(g) → Ca(HCO3)2(aq)
    4. Observations:
      1. Bubbling observed in both test tubes, indicating the release of CO2 gas.
      2. Passing the gas through lime water turns it milky due to the formation of calcium carbonate.
      3. Further passage of CO2 dissolves the precipitate, indicating the formation of calcium hydrogencarbonate.
    5. Conclusion: Metal carbonates and hydrogencarbonates react with acids to form a salt, carbon dioxide, and water.
    6. Forms of Calcium Carbonate: Limestone, chalk, and marble are different forms of calcium carbonate, each with distinct physical properties but the same chemical composition: CaCO3.
    7. Reaction of Metal Carbonates and Hydrogencarbonates with Acids
      1. General Reaction: Both metal carbonates and metal hydrogencarbonates react with acids to form a corresponding salt, carbon dioxide, and water. The general reaction can be written as:
        Metal carbonate/Metal hydrogencarbonate + Acid → Salt + Carbon dioxide + Water
      2. Example Reaction: A typical example is the reaction of Sodium Carbonate (Na2CO3) or Sodium Hydrogencarbonate (NaHCO3) with Hydrochloric Acid (HCl):
      3. Na2CO3 + 2HCl → 2NaCl + H2O + CO2 (using Sodium Carbonate)
      4. NaHCO3 + HCl → NaCl + H2O + CO2 (using Sodium Hydrogencarbonate)

    2.1.4 How do Acids and Bases React with each other?

    Activity 2.6: Acid-Base Neutralization Experiment
    1. Objective of Activity 2.6: To demonstrate how acids and bases react with each other, specifically observing the neutralization reaction.
    2. Experiment Setup:
      1. Begins with dilute NaOH (a base) in a test tube.
      2. Addition of phenolphthalein, an indicator that turns pink in basic solutions.
    3. Observations and Interpretations:
      • Initial pink color of the solution: Indicates the basic nature of the NaOH solution.
      • Gradual addition of dilute HCl (an acid): The pink color fades, demonstrating the neutralization of the base by the acid.
      • The color change of phenolphthalein: Phenolphthalein changes color based on the pH of the solution. It's pink in basic solutions and colorless in acidic environments. The fading of the pink color indicates the shift of the solution's pH from basic towards neutral.
      • Re-addition of NaOH: The reappearance of the pink color upon adding more NaOH suggests that the solution's pH has shifted back to basic.
    4. Chemical Reaction Involved:

      The reaction of NaOH with HCl is a classic example of a neutralization reaction where an acid (HCl) and a base (NaOH) react to form a salt (NaCl) and water (H2O).

      The general equation for a neutralization reaction is: Base + Acid → Salt + Water.

      Chemical Equation: NaOH (aq) + HCl (aq) → NaCl (aq) + H2O (l)

    5. Concept of Neutralization:

      Neutralization is the process where an acid and a base react to form water and a salt, effectively neutralizing each other's properties. This reaction is important in various chemical processes and in everyday life, such as in medicine and environmental management.

    6. Indicator's Role:

      Phenolphthalein serves as an indicator to visually demonstrate the pH change during the reaction. It's a practical tool to understand the acid-base balance in a given solution.

    7. Application and Significance:

      This activity illustrates the fundamental principle of acid-base chemistry and the practical use of indicators. Understanding neutralization is crucial in various fields, including chemistry, biology, medicine, and environmental science. This experiment effectively demonstrates the neutralizing effect of acids and bases on each other and the practical application of indicators in visualizing these reactions.

    Decomposition Reaction

    Let's write and balance the chemical equation for the reaction described in Activity 2.7, where copper oxide reacts with hydrochloric acid.

    Given Reaction:

    • Copper oxide ( CuO ) reacts with dilute hydrochloric acid ( HCl ) to form copper(II) chloride ( CuCl2​) and water (H2O)

    Unbalanced Chemical Equation: CuO (s) + HCl (aq) → CuCl2 ​(aq) + H2​O (l)
    Balancing the Equation:

    1. Copper (Cu): One atom on both sides – balanced.
    2. Oxygen (O): One atom on both sides – balanced.
    3. Chlorine (Cl): There are two chlorine atoms in CuCl 2 but only one in HCl . Therefore, we need to have two HCl  molecules to balance chlorine.
    4. Hydrogen (H): After balancing chlorine, we will have two hydrogen atoms from the two HCl  molecules, which are balanced with the two hydrogen atoms in H2O.
    Balanced Chemical Equation: CuO (s) + 2HCl (aq) → CuCl 2 ​(aq) + H 2​O (l)

    Conclusion: This reaction illustrates that metallic oxides, like CuO, react with acids to give salts and water. Therefore, metallic oxides are considered basic oxides, as they exhibit properties similar to bases in their reactions with acids.

    Reaction of a Non-metallic Oxide with Base

    1. Example Reaction (Activity 2.5): The reaction between carbon dioxide (CO2, a non-metallic oxide) and calcium hydroxide (lime water, a base) is used as an example.
    2. Chemical Process:
      • Reaction Formula: Ca(OH)2 (aq) + CO2 (g) → CaCO3 (s) + H2O (l)
      • This reaction involves calcium hydroxide reacting with carbon dioxide to produce calcium carbonate (a salt) and water.
    3. Conclusion on Non-metallic Oxides:
      • Non-metallic oxides, like CO2, are acidic in nature as they react with bases to form salts and water, similar to the reaction of acids.
    4. Significance:
      • Understanding the behavior of non-metallic oxides is crucial for various chemical processes, environmental studies, and industrial applications.
      • This knowledge assists in categorizing compounds as acidic or basic, fundamental in the study of chemistry.

    What Do All Acids and All Bases Have in Common?

    In Section 2.1, it was observed that all acids exhibit similar chemical properties. This is primarily due to the presence of hydrogen in acids. An activity was conducted to investigate whether all compounds containing hydrogen are acidic.

    Activity 2.8 : Overview

    1. Objective: To determine if compounds containing hydrogen are acidic.
    2. Experiment Setup: Solutions of glucose, alcohol, hydrochloric acid (HCl), and sulphuric acid (H2SO4) were tested. Two nails were fixed on a cork in a beaker and connected to a 6-volt battery through a bulb and switch.
    3. Procedure:
      • Dilute HCl and sulphuric acid were poured into the beaker, and the current was switched on.
      • The experiment was repeated separately with glucose and alcohol solutions.
    4. Observations:
      • The bulb glowed with acid solutions, indicating the flow of electric current.
      • Glucose and alcohol solutions did not conduct electricity, as the bulb did not glow.
    5. Conclusion: The glowing bulb in the presence of acids suggests that acids conduct electricity due to ionization. Acids contain H+ ions as cations, which are responsible for their acidic properties.

    The experiment concludes that the presence of H+ ions in a solution is indicative of acidic properties, differentiating acids from non-acidic compounds like glucose and alcohol.

    2.2 What Do All Acids and All Bases Have in Common?

    Based on Section 2.2 and the details from Activity 2.8, we can summarize the common properties of acids and bases and what they have in common. The key concept here is the generation of ions in solution, which leads to the characteristic properties of acids and bases.
    1. Common Feature in Acids:
      • All acids generate hydrogen gas on reacting with metals, indicating that hydrogen (H⁺) ions are common to all acids.
      • In Activity 2.8, when acids like hydrochloric acid (HCl) and sulfuric acid (H₂SO₄) are tested, they conduct electricity, as evidenced by the glowing of a bulb in an electrical setup. This conductivity is due to the presence of ions in the solution.
    2. Acidic Solutions and Conductivity:
      • The conductivity of acidic solutions is due to the dissociation of acids into their respective ions in solution. For example, HCl dissociates into H⁺ and Cl⁻ ions.
      • This ionization is responsible for the acidic properties of these compounds.
    3. Testing Non-Acidic Compounds:
      • When solutions of non-acidic compounds like glucose and alcohol are tested, the bulb does not glow, indicating no electrical conductivity. This is because these solutions do not ionize into charged particles in water.
    4. Experiment with Bases:
      • Repeating the same activity with alkalis (bases) like sodium hydroxide (NaOH) or calcium hydroxide (Ca(OH)₂) will show that the bulb glows, indicating that bases also conduct electricity in solution.
    5. Conclusion from Activity:
      • The common feature in acids is the production of hydrogen ions (H⁺) in solution, leading to their acidic properties.
      • Bases, on the other hand, generate hydroxide ions (OH⁻) in solution.
      • Both acids and bases conduct electricity in their aqueous solutions due to the presence of these ions.
    This understanding is crucial in the study of acid-base chemistry, as it provides insight into the nature and behavior of these substances in different conditions, particularly in their ability to conduct electricity due to ionization.

    Acids, Bases, and their Behavior in Water Solutions

    1. Ion Production in Acids and Bases:
      • Acids and bases produce ions in aqueous solutions.
      • Acids generate hydrogen ions (H⁺) in water, which exist as hydronium ions (H₃O⁺).
      • Bases generate hydroxide ions (OH⁻) in water.
      • Example: HCl + H2O → H3O+ + Cl
    2. Activity 2.9: Acid in a Non-Aqueous Environment:
      • Testing dry HCl gas with both dry and wet blue litmus paper shows that acidic character is prominent only in the presence of water.
      • This suggests that hydrogen ions in HCl are produced only in the presence of water.
    3. Alkalis: Bases soluble in water:
      • Not all bases dissolve in water. Those that do are called alkalis (e.g., NaOH, KOH).
      • Alkalis are soapy to touch, bitter, and corrosive.
    4. Neutralization Reaction:
      • The neutralization reaction can be viewed as the reaction of H⁺ ions from the acid and OH⁻ ions from the base to form water (H₂O).
      • Example:

        Acid + Base → Salt + Water
        H [ X + M ] OH → MX + HOH
        H + (aq) + OH (aq) → H 2O(l)

      Dissolving Acids and Bases in Water

    Activity 2.10
  3. Objective : To observe the temperature changes when an acid or a base is dissolved in water, illustrating the exothermic nature of this process.
  4. Procedure:
    • Measure 10 mL of water into a beaker.
    • Add a few drops of concentrated sulfuric acid (H₂SO₄) to the water and swirl the beaker gently.
    • Touch the base of the beaker to feel any temperature change.
    • Repeat the experiment with sodium hydroxide (NaOH) pellets.
  5. Observations:
    • When adding H₂SO₄ or NaOH to water, a noticeable increase in temperature is felt at the base of the beaker.
    • This indicates that the process of dissolving an acid (H₂SO₄) or a base (NaOH) in water is exothermic, releasing heat.
  6. Safety Precautions:
    • It's crucial to add the acid or base to water, not the other way around, to control the exothermic reaction.
    • Adding water to concentrated acid can cause the mixture to splash and may result in burns or break the glass container due to excessive localized heating.
  7. Chemical Implications of Dilution:
    • The process of mixing an acid or base with water reduces the concentration of ions (H₃O⁺/OH⁻) per unit volume.
    • This process is known as dilution, and it results in the acid or base becoming diluted.
  8. Practical Implications:
    • Understanding the exothermic nature of dissolving acids and bases in water is important for handling these substances safely in both laboratory and industrial settings.
    • The heat released during these reactions can have implications for the design of containers and the protocols for handling concentrated acids and bases.

  9. 2.3 HOW STRONG ARE ACID OR BASE SOLUTIONS?

    The strength of acids and bases in solutions can be understood through their ion concentration, specifically hydrogen ions (H⁺) for acids and hydroxide ions (OH⁻) for bases. This is where the concept of pH and the use of a universal indicator come into play.


    pH Scale and Universal Indicator:

    1. pH Scale:
      • The pH scale measures the concentration of hydrogen ions in a solution.
      • It ranges from 0 (very acidic) to 14 (very alkaline), with 7 being neutral.
      • The term 'pH' comes from 'potenz' in German, meaning power or potential.
      • Lower pH values indicate higher hydronium ion concentration and hence more acidic solutions.
      • Higher pH values indicate higher OH⁻ ion concentration, suggesting stronger alkaline solutions.
    2. Universal Indicator:
      • A mixture of several indicators that shows different colors at different hydrogen ion concentrations.
      • It's commonly used for measuring pH, often impregnated in paper strips.


    Activity 2.11: Testing pH Values

    • Objective: To test and record the pH values of various solutions and determine their acidic or basic nature.
    • Method: Using pH paper impregnated with a universal indicator, the pH of different substances like saliva, lemon juice, coffee, tap water, and solutions of NaOH and HCl is tested.
    • Expected Outcome: The color change on the pH paper will indicate the pH value, helping to classify each substance as acidic, basic, or neutral.


    Strength of Acids and Bases:

    • Based on Ion Production:
      • Strong Acids: Acids that produce more H⁺ ions in solution are considered strong acids (e.g., hydrochloric acid).
      • Weak Acids: Acids that produce fewer H⁺ ions are considered weak acids (e.g., acetic acid).
      • Strong Bases: Bases that produce more OH⁻ ions are considered strong bases (e.g., sodium hydroxide).
      • Weak Bases: Bases that produce fewer OH⁻ ions are considered weak bases.


    Conclusion:

    • The strength of an acid or base is determined by its ability to produce ions in solution.
    • The pH scale provides a quantitative measure of this strength, indicating the acidic or basic nature of the solution.
    • Understanding these concepts is crucial for various applications in chemistry, biology, and environmental science.

    Importance of pH in Everyday Life

    Understanding the significance of pH in our daily lives reveals its crucial role in various environmental and biological processes.pH Sensitivity in Living Organisms:

    1. Human Body:
      • The human body operates optimally within a pH range of 7.0 to 7.8.
      • This pH balance is essential for various bodily functions and maintaining overall health.
    2. Plants and Animals:
      • Both plants and animals are sensitive to pH changes.
      • They can only survive and thrive within a narrow pH range.
    Environmental Impact:
    1. Acid Rain:
      • Rainwater with a pH less than 5.6 is classified as acid rain.
      • Acid rain can lower the pH of river water, adversely affecting aquatic life.
    2. Soil pH and Plant Growth:
      • The pH of soil is a critical factor for the healthy growth of plants.
      • Different plants require different pH levels in the soil for optimal growth.
    Extraterrestrial Acidity:
    • Acids in Other Planets:
      • For instance, the atmosphere of Venus is composed of thick clouds of sulfuric acid.
      • Such extreme acidic conditions raise questions about the possibility of life on planets with harsh environments.
    Practical Application: Testing Soil pH
    • Activity 2.12: Involves collecting soil samples from various locations and testing their pH.
    • Purpose: To determine the pH range required for the healthy growth of specific plants and understand the relationship between soil pH and plant species in different regions.
    Conclusion: The pH level plays a vital role in various aspects of life on Earth and potentially on other planets. From affecting the survival of aquatic life due to acid rain to influencing the growth of plants in different soil types, the balance of acidity and alkalinity is a key factor in the health and functioning of ecosystems. Understanding and monitoring pH levels is essential for environmental conservation, agriculture, and even space exploration.

    Activity 2.12

    In Activity 2.12, you are conducting an experiment to determine the pH of the soil in your region. Here are the steps and conclusions:

    1. Put about 2 g of soil in a test tube.
    2. Add 5 mL of water to the test tube.
    3. Shake the contents of the test tube to mix the soil and water.
    4. Filter the contents to remove solid particles and collect the filtrate in another test tube.
    5. Check the pH of the filtrate using universal indicator paper.

    1. pH in our digestive system: The stomach produces hydrochloric acid to aid in digestion, and antacids like magnesium hydroxide are used to neutralize excess acid when indigestion occurs.

    2. pH change as the cause of tooth decay: Tooth decay begins when the pH in the mouth drops below 5.5, leading to the corrosion of tooth enamel. Regular cleaning of the mouth, including using basic toothpaste, can help prevent tooth decay.

    3. Self-defense by animals and plants through chemical warfare: Animals like honey-bees and plants like nettles use chemical substances with varying pH levels for defense. For example, bee stings inject an acidic substance, and using a mild base like baking soda can provide relief. Nettle stings contain methanoic acid, and dock plants growing nearby can provide a remedy by having properties that neutralize the acid.

    4. Nature provides neutralization options: The example of nettles and dock plants demonstrates how nature often provides natural remedies for chemical irritations and stings. Other remedies might exist for similar situations, depending on the region and the specific irritants involved.
    It's important to note that pH plays a crucial role in various natural processes and interactions, and understanding it can help in various practical situations, as demonstrated in the provided information.

    2.4 MORE ABOUT SALTS

    2.4.1 Family of Salts

    Here are the chemical formulae of the salts mentioned in Activity 2.13:

    1. Potassium Sulphate: K2SO4
    2. Sodium Sulphate: Na2SO4
    3. Calcium Sulphate: CaSO4
    4. Magnesium Sulphate: MgSO4
    5. Copper Sulphate: CuSO4
    6. Sodium chloride: NaCl
    7. Sodium nitrate: NaNO3
    8. Sodium carbonate: Na2CO3
    9. Ammonium chloride: NH4Cl

    Now, let's identify the acids and bases from which these salts may be obtained:
    1. Potassium Sulphate: Obtained from Sulphuric acid (H2SO4) and Potassium hydroxide (KOH).
    2. Sodium Sulphate: Obtained from Sulphuric acid (H2SO4) and Sodium hydroxide (NaOH).
    3. Calcium Sulphate: Obtained from Sulphuric acid (H2SO4) and Calcium hydroxide (Ca(OH)2).
    4. Magnesium Sulphate: Obtained from Sulphuric acid (H2SO4) and Magnesium hydroxide (Mg(OH)2).
    5. Copper Sulphate: Obtained from Sulphuric acid (H2SO4) and Copper oxide (CuO).
    6. Sodium chloride: Obtained from Hydrochloric acid (HCl) and Sodium hydroxide (NaOH).
    7. Sodium nitrate: Obtained from Nitric acid (HNO3) and Sodium hydroxide (NaOH).
    8. Sodium carbonate: Obtained from Carbonic acid (H2CO3) and Sodium hydroxide (NaOH).
    9. Ammonium chloride: Obtained from Hydrochloric acid (HCl) and Ammonia (NH3).

    Now, let's identify the families of salts:
    1. Sodium Salts:
      • Sodium Sulphate (Na2SO4)
      • Sodium chloride (NaCl)
      • Sodium nitrate (NaNO3)
      • Sodium carbonate (Na2CO3)
    2. Potassium Salts:
      • Potassium Sulphate (K2SO4)
    3. Calcium Salts:
      • Calcium Sulphate (CaSO4)
    4. Magnesium Salts:
      • Magnesium Sulphate (MgSO4)
    5. Copper Salts:
      • Copper Sulphate (CuSO4)
    6. Ammonium Salt:
      • Ammonium chloride (NH4Cl)
    The salts within each group have the same positive or negative radicals, which are the cations (positive) and anions (negative) that make up the salts. Therefore, we can identify six families of salts among the ones listed in this activity.

    2.4 MORE ABOUT SALTS

    Salts and pH

    2.4.2 - pH of Salts

    Activity 2.14
    - Collect the following salt samples – sodium chloride (NaCl), potassium nitrate (KNO3), aluminium chloride (AlCl3), zinc sulphate (ZnSO4), copper sulphate (CuSO4), sodium acetate (CH3COONa), sodium carbonate (Na2CO3), and sodium hydrogencarbonate (NaHCO3).
    - Check their solubility in water (use distilled water only).
    - Check the action of these solutions on litmus and find the pH using a pH paper.
    - Which of the salts are acidic, basic or neutral? Identify the acid or base used to form the salt.
    - Report your observations in Table 2.4.
    Salts of a strong acid and a strong base are neutral with pH value of 7. On the other hand, salts of a strong acid and weak base are acidic with pH value less than 7 and those of a strong base and weak acid are basic in nature, with pH value more than 7.

    Salt Solubility in Water Effect on Litmus pH Value Nature Acid/Base Used to Form Salt
    Sodium chloride Soluble No change 7 (neutral) Neutral HCl + NaOH
    Potassium nitrate Soluble No change 7 (neutral) Neutral HNO3 + KOH
    Aluminium chloride Soluble Turns red (acidic) < 7 (acidic) Acidic HCl + Al(OH)3
    Zinc sulphate Soluble No change 7 (neutral) Neutral H2SO4 + Zn(OH)2
    Copper sulphate Soluble Turns blue (basic) > 7 (basic) Basic H2SO4 + Cu(OH)2
    Sodium acetate Soluble No change 7 (neutral) Neutral CH3COOH + NaOH
    Sodium carbonate Soluble Turns blue (basic) > 7 (basic) Basic H2CO3 + NaOH
    Sodium hydrogencarbonate Soluble Turns blue (basic) > 7 (basic) Basic H2CO3 + NaOH

    In this table:

    • Solubility indicates whether the salt dissolves in water.
    • Effect on Litmus tells you whether the solution turns red (acidic), blue (basic), or has no change (neutral) on litmus paper.
    • pH Value gives the approximate pH of the solution.
    • Nature describes whether the salt is acidic, basic, or neutral based on the pH.
    • The last column identifies the acid (if any) and the base used to form the salt.
    Remember that the pH values are approximate and may vary slightly depending on the concentration of the solutions and the accuracy of your pH paper.

    2.4.3 Chemicals from Common Salt
    • Salt Formation: The combination of hydrochloric acid and sodium hydroxide solution results in the formation of sodium chloride, commonly known as table salt. It is a staple in food.
    • Neutral Salt: Sodium chloride, as observed in the previous activity, is classified as a neutral salt because it has a pH close to 7.
    • Seawater Composition: Seawater contains a mixture of various dissolved salts, including sodium chloride, along with other minerals and elements.
    • Sodium Chloride Separation: Sodium chloride is separated from other salts present in seawater through various methods.
    • Rock Salt: Solid deposits of salt, known as rock salt, are found in various regions around the world. These salt crystals are often brown due to impurities.
    • Formation of Rock Salt: Beds of rock salt were created during ancient times when seas dried up, leaving behind these deposits.
    • Mining Process: Rock salt is extracted from the Earth in a manner similar to coal mining.
    • Historical Significance: Sodium chloride, also known as common salt, held significant symbolic importance during Mahatma Gandhi's Dandi March, which was a pivotal event in India's struggle for independence.

    Common Salt and Its Uses

    1. Common Salt as a Raw Material:

    • Common salt serves as a crucial raw material for various everyday substances, including:
      1. Sodium hydroxide
      2. Baking soda
      3. Washing soda
      4. Bleaching powder


    2. Sodium Hydroxide Production:

    • Sodium hydroxide (NaOH) is produced by passing electricity through an aqueous solution of sodium chloride (brine) in a process known as the chlor-alkali process.
    • The name "chlor-alkali" refers to the products formed:
      1. "Chlor" for chlorine
      2. "Alkali" for sodium hydroxide

    Chemical Equation: 2NaCl(aq) + 2H2O(l) → 2NaOH(aq) + Cl2(g) + H2(g)

    • During this process:
      1. Chlorine gas (Cl2) is released at the anode.
      2. Hydrogen gas (H2) is released at the cathode.
      3. Sodium hydroxide solution (NaOH) is formed near the cathode.
    • All three products have various useful applications.

    3. Bleaching Powder Production:

    • Chlorine gas produced during the electrolysis of aqueous sodium chloride is used for manufacturing bleaching powder.
    • Bleaching powder is produced by the action of chlorine on dry slaked lime [Ca(OH)2].

    Chemical Equation: Ca(OH)2 + Cl2 → CaOCl2 + H2O

    • Uses of Bleaching Powder: Bleaching powder has several applications:
      1. It's used for bleaching cotton and linen in the textile industry.
      2. It's employed for bleaching wood pulp in paper factories.
      3. It's used for bleaching washed clothes in laundry.
      4. It serves as an oxidizing agent in many chemical industries.
      5. It's utilized to purify drinking water, making it free from harmful germs.
    Baking Soda and Its Uses

    4. Baking Soda Usage:

    Baking soda, chemically known as sodium hydrogencarbonate (NaHCO3), is commonly used in kitchens for various purposes. It is used to make crispy pakoras, expedite cooking, and add a pleasant taste to food.

    Production of Baking Soda:

    • Baking soda is produced using sodium chloride (NaCl) as one of its raw materials. The reaction involves the following chemical equation:
    • NaCl + H2O + CO2 + NH3 → NH4Cl + NaHCO3 (Ammonium chloride + Sodium hydrogencarbonate)

    pH of Sodium Hydrogencarbonate:

    • Sodium hydrogencarbonate is mildly basic and non-corrosive. In Activity 2.14, its pH can be observed to be alkaline. This property makes it suitable for neutralizing acids.

    Heating of Sodium Hydrogencarbonate:

    • When sodium hydrogencarbonate is heated during cooking, it undergoes a reaction that produces sodium carbonate (Na2CO3), water (H2O), and carbon dioxide (CO2): 2NaHCO3 → Na2CO3 + H2O + 2CO2

    Household Uses of Baking Soda:

    • Baking Powder: Baking soda is used to make baking powder, which is a mixture of baking soda and a mild edible acid like tartaric acid. When heated or mixed with water, this reaction occurs:
      • NaHCO3 + H+ → CO2 + H2O+ Sodium salt of acid (From any acid)

      The release of carbon dioxide gas causes bread or cake to rise, making them soft and spongy.

    • Antacid: Sodium hydrogencarbonate is an ingredient in antacids. Its alkaline nature allows it to neutralize excess stomach acid, providing relief from indigestion.
    • Fire Extinguishers: Sodium hydrogencarbonate is used in soda-acid fire extinguishers for firefighting purposes.


    5. Washing Soda 

    The 10H 2 O  in the compound Na 2 CO 3 10 H 2 O (washing soda) signifies that there are 10 water molecules associated with each sodium carbonate ( Na 2 CO 3 ) molecule. This is referred to as water of crystallization, which is water that is included in the crystal structure of a compound. These water molecules are not just physically trapped, but they are a part of the crystal structure of the compound, giving it a specific geometric shape.
    This does not mean that the Na 2 CO 3 is wet. Rather, the water molecules are chemically bonded to the sodium carbonate, and the compound is typically in the form of a powder. This water of crystallization is important for the compound's properties and stability. When you heat washing soda, these water molecules can be driven off, leaving anhydrous sodium carbonate, which is without water.As for its uses, washing soda is an important industrial and household chemical:

    1. In Industries:
      • Glass Industry: Washing soda is used in the production of glass.
      • Soap and Detergent Industry: It's a major component in soap and detergent manufacturing.
      • Paper Industry: It's used in the process of making paper.
    2. Manufacture of Sodium Compounds:
      • Washing soda is used as a starting material for producing other sodium compounds like borax.
    3. Cleaning Agent:
      • It is used as a cleaning agent for domestic purposes due to its ability to cut grease, remove stains, and neutralize odors.
    4. Water Softening:
      • Washing soda is used to remove the 'permanent hardness' of water, which is caused by the presence of dissolved calcium and magnesium salts. It does so by precipitating these salts out of the water.

    2.4.4 Are the Crystals of Salts really Dry?

    Activity 2.15
    1. Activity with Copper Sulphate (CuSO₄·5H₂O):
      • Heating Copper Sulphate Crystals: When you heat copper sulphate crystals, which are blue due to water of crystallization, the water molecules are driven off as the heat provides enough energy to break the bonds holding the water in the crystal structure.
      • Color Change: Upon heating, the color of hydrated copper sulphate changes from blue to white, which is the color of anhydrous copper sulphate (CuSO₄ without water).
      • Observation of Water Droplets: The water droplets observed in the boiling tube come from the water of crystallization that has been released from the copper sulphate crystals due to heating.
      • Rehydration: When water is added to the anhydrous white copper sulphate, the blue color is restored, indicating that the water of crystallization has been reabsorbed into the crystal structure, reforming the hydrated compound.
    2. Water of Crystallisation:
      • This is the term for water molecules that are integrated into the crystal structure of a salt in a fixed ratio. It is not liquid water, but part of the solid crystal lattice.
      • Copper Sulphate: CuSO₄·5H₂O means there are five water molecules per formula unit of copper sulphate.
      • Gypsum: Similarly, gypsum (CaSO₄·2H₂O) contains two water molecules per formula unit of calcium sulphate.
    3. Na₂CO₃ · 10H₂O : With this understanding, we can say that the crystals of Na₂CO₃ · 10H₂O (washing soda) are not "wet" in the usual sense. They contain water of crystallization, which is part of their crystalline structure. So, even though the crystals appear dry, they contain water molecules within their crystal lattice.
    4. Gypsum and Its Uses:
      • Gypsum, or calcium sulfate dihydrate (CaSO₄·2H₂O), has two water molecules as water of crystallization.
      • When gypsum is heated, it loses water and becomes calcium sulfate hemihydrate, commonly known as plaster of Paris (CaSO₄·½H₂O).
      • Gypsum is used in the construction industry for making drywall or plasterboard and as a soil conditioner in agriculture. It's also a primary material in the creation of plaster of Paris, which is used for castings and moldings.
    The activity and the examples given in the text are meant to illustrate the presence and importance of water of crystallization in certain hydrated salts. The concept is crucial in understanding the properties of these salts and their behavior under various conditions, such as heating.


    Plaster of Paris (Calcium sulfate hemihydrate, CaSO₄·½H₂O)
    • When gypsum (CaSO₄·2H₂O) is heated to 373 K, it loses part of its water of crystallization and becomes calcium sulfate hemihydrate, known as Plaster of Paris.
    • Plaster of Paris is used by doctors as a plaster for setting broken bones due to its ability to harden upon mixing with water.
    • It is a white powder that, when mixed with water, reverts to gypsum, forming a hard solid mass, which is desirable for casts.

    Chemical Reaction: CaSO 4 1 2 H 2 O + 1 2 H 2 O CaSO 4 2 H 2 O
                                                (Plaster of Paris)   +  (Water)  →           (Gypsum)
    • The reaction shows that Plaster of Paris and water combine to form gypsum, the original material before heating.

    Water of Crystallisation in Plaster of Paris:
    • Notation of half a water molecule (½H₂O) indicates that two formula units of CaSO₄ share one water molecule in their crystalline form.
    • This is possible because the water molecule can be split between two units, and it does not exist as a half molecule but as part of a larger crystalline structure.

    Uses of Plaster of Paris:
    • Medical Applications: Used for making casts to immobilize broken bones.
    • Art and Decoration: Utilized in making toys, decorative materials, and for creating smooth surfaces on walls and ceilings before painting.
    • Manufacturing: Involved in the production of ornamental fixtures and to give a finishing touch to buildings and interiors.

    Question on Water of Crystallisation:
    • Understanding Half a Water Molecule: The concept of half a water molecule arises from the stoichiometry of the substance, where the crystalline lattice includes one water molecule for every two formula units of CaSO₄, not literally half a water molecule.

    Further Inquiry:
    • The text encourages exploring why calcium sulfate hemihydrate is specifically called 'Plaster of Paris'. This name originates from large deposits of gypsum found in the Montmartre district of Paris, which provided an abundant source of the material for making Plaster of Paris. Historically, this material was extensively used for construction and decorative purposes in Paris, leading to its common name.The notes encapsulate the information about Plaster of Paris as presented in the educational material, highlighting its chemical properties, transformation from gypsum, and practical applications in various fields. The text also prompts a deeper exploration of the nomenclature and encourages understanding the chemistry behind water of crystallization.

    CBSE Class 10 Science Chapter 1 - Chemical Reactions and Equations Notes

    Class 10 CBSE Important Questions and Answers Chapter 1 - Chemical Reactions and Equations


    Class 10 NCERT Chapter 1 - Chemical Reactions and Equations AJs Chalo Seekhen Class 10 CBSE Important Questions and Answers Chapter 1 - Chemical Reactions and Equations ajs notes history chapter 1  ajs class 10 chapter 1 imp questions

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